DID YOU KNOW?
The
life of concrete is limited by a number of
disintegrating effects:
Weathering:
Weathering by rain and frost action is chiefly a
function of water-tightness or impermeability, since
leach and attack by the carbonic and other acids present
in rainwater, and disruption by frost action, depend on
the penetration of water into the surface.
Chemical attack such as industrial chemicals and wastes;
sewage; animal and vegetable oils, fats, grease; milk;
and sugars. Wear by abrasion from foot and
vehicular traffic, by wave actions, and by water-borne
and wind-borne particles.
Voids:
Concrete has the tendency to be porous due to the
presence of voids formed during or after placing. It is
usually necessary in order to obtain workable mixes, to
use far more water than is actually necessary for
chemical combination with the cement. This water
occupies space, and when it later dries out, it leaves
behind air voids.
Gases:
Gases such as sulphur dioxide and carbon dioxide in damp
situations, attack concrete. Sulphuric acid also attacks
concrete, but the attack from sulphuric acid is likely
to be accompanied by abrasion. Sulphates of sodium
potassium, magnesium and ammonium may cause serious
damage to Portland cement concrete in the presence of
moisture. This begins by expansion within the concrete,
which may be enough to cause general expansion in the
member.
Cracking:
Cracking and disruption follow. Cracks provide a path
for soluble chemicals to migrate into the interior of
the "Generally, inorganic acids are destructive to
concrete... may also be released from some salts..."
structure causing deterioration of the concrete.
Fertilizers often contain ammonium, potassium and
magnesium sulphates. Generally, inorganic acids are
destructive to concrete. These may also be released from
some salts such as ammonium chloride and ammonium
nitrate by interaction with lime. Leaching then follows.
A number of fertilizers are soluble in water, enabling
the chemical easy pathway to the interior of the
concrete. Although petroleum oils, are not known to
cause extensive damage to concrete, they do penetrate
into the pores and cause unsightly staining, with
subsequent high maintenance cleaning as well as possible
contamination of the soil below leading to environmental
issues. Organic acids such as stearic, oleic, lactic and
tannic all attack concrete. Lactic substances which are
derived from dairy product have a most destructive
effect. Vegetable oils attack, molasses, sugar, syrup,
glucose have a fair degree of attack, acetic acid which
occurs in vinegar and tartaric acid which occurs in some
fruit juices all attack concrete.
Sewage:
Sewage normally has an alkaline tip reaction and is
harmless, but it may become acid by contamination with
factory wastes and will then attack concrete. The
concrete along the top of sewers can be severely
attacked as the result of hydrogen sulphide gas being
evolved from the stale sewage. The hydrogen sulphide is
oxidized by anaerobic bacteria to form sulphuric acid
which condenses on the walls of the structure. The
attack may be rapid particularly in warm conditions and
where ventilation is poor.